testdb=# create table t (id int);
CREATE TABLE
testdb=# insert into t values (1);
INSERT 0 1
testdb=# insert into t values (2);
INSERT 0 1
testdb=# insert into t values (3);
INSERT 0 1
testdb=#
testdb=# insert into t values (NULL);
INSERT 0 1
testdb=# select * from t order by id asc;
 id
----
  1
  2
  3
(4 rows)
testdb=# select * from t order by id desc;
 id
----
  3
  2
  1
(4 rows)
testdb=# select * from t order by (id is not null) asc, id;
 id
----
  1
  2
  3
(4 rows)
testdb=# select * from t order by (id is not null) desc, id;
 id
----
  1
  2
  3
(4 rows)
testdb=# select * from t order by (id is not null) asc, id desc;
 id
----
  3
  2
  1
(4 rows)
testdb=# select * from t order by (id is not null) desc, id desc;
 id
----
  3
  2
  1
(4 rows)